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Recent Publications


  • A Tertiary Amine as A Hydride Donor: Trichlorosilyl Triflate-mediated Conjugate Reduction of Unsaturated Ketones.
    Kotani, S.; Osakama, K.; Sugiura, M.; Nakajima, M. Org. Lett. 2011, 13, 3968-3971.

  • Enantioselective Evans-Tishchenko Reduction of β-Hydroxyketone Catalyzed by Lithium Binaphtholate.
    Ichibakase, T.; Nakatsu, M.; Nakajima, M. Molecules 2011, 52, 5008-5019.

  • Enantioselective Double Aldol Reaction Catalyzed by Chiral Phosphine Oxide.
    Shimoda, Y.; Kotani, S.; Sugiura, M.; Nakajima, M. Chem. Eur. J. 2011, 17, 7992-7995.

  • Trichlorosilyl Triflate for Enantioselective Direct-type Aldol Reaction with Chiral Phosphine Oxide.
    Kotani, S.; Aoki, S.; Sugiura, M.; Nakajima, M. Tetrahedron Lett. 2011, 52, 2834-2836.

  • Lithium Acetylides as Alkynylating Reagents for the Enantioselective Alkynylation of Ketones Catalyzed by Lithium Binaphtholate.
    Tanaka, K.; Kukita, K.; Ichibakase, T.; Kotani, S.; Nakajima, M. Chem Commun. 2011, 47, 5614-5616.

  • Direct Enantioselective Aldol-Tishchenko Reaction Catalyzed by Chiral Lithium Diphenylbinaphtholate.
    Ichibakase, T.; Nakajima, M. Org. Lett. 2011, 13, 1579-1581.

  • Synthesis of γ-Amino Alcohols from Aldehydes, Enamines, and Trichlorosilane using Lewis Base Catalysts.
    Kashiwagi, T.; Kotani, S.; Sugiura, M.; Nakajima, M. Tetrahedron 2011, 67, 531-539.

  • Enantioselective Conjugate Addition of Boronic Acids to Enones Catalyzed by O-Monoacyltartaric Acids.
    Sugiura, M.; Tokudomi, M.; Nakajima, M.Chem. Commun. 2010, 46, 7799-7800.

  • Enantioselective Alkynylation of Carbonyl Compounds with Trimethoxysilylalkynes Catalyzed by Lithium Binaphtholate.
    Ueda, T.; Tanaka, K.; Ichibakase, T.; Orito, Y.; Nakajima, M. Tetrahedron 2010, 66, 7726-7731.

  • “Roofed” β-Iminodisulfides as New Chiral Ligands for Palladium-Catalyzed, Asymmetric Allylic Alkylation.
    Matsunaga, H.; Tokuda, R.; Nakajima, M.; Ishizuka, T. Chem. Pharm. Bull. 2010, 58, 1419-1421.

  • 有機オキシド化合物を触媒とする直接的不斉アルドール反応の開発.
    中島 誠, 化学工業, 2010, 61, 662-666.

  • Development of Chiral Dinitrones as Modular Lewis Base Catalysts: Asymmetric Allylation of Aldehydes with Allyltrichlorosilanes.
    Oh, Y. S.; Kotani, S.; Sugiura, M.; Nakajima, M. Tetrahedron: Asymmetry 2010, 21, 1833-1835.

  • DMAP-catalyzed Cyanation of Aldehydes and Ketones with Ethyl Cyanoformate.
    Aoki, S.; Kotani, S.; Sugiura, M.; Nakajima, M. Tetrahedron Lett. 2010, 51, 3547-3549.

  • Enantioselective Alkynylation of Ketones with Trimethoxysilylalkynes using Lithium Binaphtholate as a Catalyst.
    Tanaka, K.; Ueda, T.; Ichibakase, T.; Nakajima, M. Tetrahedron Lett. 2010, 51, 2168-2169.

  • Diastereo- and Enantioselective Reductive Aldol Reaction with Trichlorosilane Using Chiral Lewis Bases as Organocatalysts.
    Sugiura, M.; Sato, N.; Sonoda, Y.; Kotani, S.; Nakajima.; M. Chem. Asian J. 2010, 5, 478-481.

  • 第四級不斉炭素を構築するアルドール反応.
    中島 誠, pp 248-249 「使える！有機合成反応241実践ガイド」丸岡啓二, 野崎京子, 石井康敬, 大 寺純蔵, 富岡 清監修,　化学同人, 2010.

  • エノンの不斉還元的アルドール反応.
    杉浦正晴, 中島 誠, pp 472-473「使える！有機合成反応241実践ガイド」丸岡啓二, 野崎京子, 石井康 敬, 大寺純蔵, 富岡 清監修,　化学同人, 2010.

  • Novel Enantioselective Direct Aldol-type Reaction Promoted by Chiral Phosphine Oxide as an Organocatalyst.
    Kotani, S.; Shimoda, Y.; Sugiura, M.; Nakajima, M. Tetrahedron Lett. 2009, 50, 4602-4605.

  • Enantioselective Aldol Reaction of Silyl Ketene Acetals Promoted by a Lewis Base-activated Lewis Acid Catalyst.
    Shimoda, Y.; Tando, T.; Kotani, S.; Sugiura, M.; Nakajima, M. Tetrahedron: Asymmetry, 2009, 20, 1369-1370.

  • Asymmetric Synthesis of 4H-1,3-Oxazines: Enantioselective Reductive Cyclization of β-Amino Enones with Trichlorosilane Catalyzed by Chiral Lewis Bases.
    Sugiura, M.; Kumahara, M.; Nakajima, M. Chem. Commun. 2009, 3585-3587.

  • クロロシリル化合物を活性 化する塩基触媒による不斉合成反応.
    中島　誠, pp131-136 「フロンティア21　進化を続ける有機触媒」丸岡啓二監修,　化学同人, 2009.

  • A Chiral "Roofed" cis-Diamine-Ru(II) Complex: An Efficient Catalyst for Asymmetric Transfer Hydrogenation of Ketimines.
    Matsunaga, H.; Nakanishi, K.; Nakajima, M.; Kunieda, T.; Ishizuka, T. Heterocycles, 2009, 78, 617-622.

  • Lewis Base-catalyzed Conjugate Reduction and Reductive Aldol Reaction of α,β-Unsaturated Ketones Using Trichlorosilane.
    Sugiura, M.; Sato, N.; Kotani, S.; Nakajima, M. Chem. Commun. 2008, 4309-4311.

  • Enantioselective Construction of Quaternary Asymmetric Carbon Centers Using an Aldol Reaction of Trimethoxysilyl Enol Ethers Catalyzed by Lithium Binaphtholate.
    Ichibakase, T.; Orito, Y.; Nakajima, M. Tetrahedron Lett. 2008, 49, 4427-4429.

  • First Asymmetric Abramov-type Phosphonylation of Aldehydes with Trialkyl Phosphites Catalyzed by Chiral Lewis Bases.
    Nakanishi, K.; Kotani, S.; Sugiura, M.; Nakajima, M. Tetrahedron 2008, 64, 6415-6419.

  • Chiral Phosphine Oxide BINAPO as a Lewis Base Catalyst for Asymmetric Allylation and Aldol Reaction of Trichlorosilyl Compounds.
    Kotani, S.; Hashimoto, S.; Nakajima, M. Tetrahedron 2007, 63, 3122-3132.

  • Catalytic Enantioselective Tandem Carbonyl Ylide Formation/1,3-Dipolar Cycloaddition Reactions of α-Diazo Ketones with Aromatic Aldehydes using Dirhodium(II) Tetrakis[N-benzene-fused-phthaloyl-(S)-valinate].
    Tsutsui, H.; Shimada, N.; Abe, T.; Anada, M.; Nakajima, M.; Nakamura, S.; Nambu, H.; Hashimoto, S. Adv. Synth. Catal. 2007, 349, 521-526.

  • Enantioselective Aldol Reactions of Trichlorosilyl Enol Ethers Catalyzed by the Chiral Phosphine Oxide BINAPO.
    Kotani, S.; Hashimoto, S.; Nakajima, M. Synlett 2006, 1116-1118.

  • Lewis Base Catalyzed Asymmetric Reactions Involving Hypervalent Silicate Intermediates.
    Orito, Y.; Nakajima, M. Synthesis 2006, 1391-1401.

  • Chiral Base-Catalyzed Aldol Reaction of Trimethoxysilyl Enol Ethers: Effect of Water as an Additive on Stereoselectivities.
    Orito, Y.; Hashimoto, S.; Ishizuka, T.; Nakajima, M. Tetrahedron 2006, 62, 390-400.

  • N-オキシド・ホスフィンオキシドを触媒とする不斉合成反応.
    中島　誠 pp59-70「有機分子触媒の新展開」柴崎正勝監修　シー・エム・シー出版, 2006.

  • Chiral Phosphine Oxide as a Catalyst for Enantioselective Allylation of Aldehydes with Allyltrichlorosilane.
    Nakajima, M.; Kotani, S.; Ishizuka, T.: Hashimoto, S. Tetrahedron Lett. 2005, 46, 157-159.

  • Sterically Congested 'Roofed' 2-Thiazolines as New Chiral Ligands for Copper(II)-Catalyzed Asymmetric Diels-Alder Reactions.
    Yamakuchi, M.; Matsunaga, H.; Tokuda, R.; Ishizuka, T.; Nakajima, M.; Kunieda, T. Tetrahedron Lett. 2005, 46, 4019-4022.

  • Asymmetric Ring Opening of meso-Epoxides Catalyzed by the Chiral Phosphine Oxide BINAPO.
    Tokuoka, E.; Kotani, S.; Matsunaga, H.; Ishizuka, T.; Hashimoto, S.; Nakajima, M. Tetrahedron: Asymmetry 2005, 16, 2391-2392.

  • Sterically Congested 'Roofed' 2-Iminothioethers as New Chiral Ligands for Palladium-catalyzed Asymmetric Allylic Alkylation.
    Tokuda, R.; Matsunaga, H.; Ishizuka, T.; Nakajima, M.; Kunieda, T. Heterocycles 2005, 66, 135-141.

  • Enantioselective Aldol Reactions of Trichlorosilyl Enol Ethers Catalyzed by Chiral N,N'-Dioxides and Monodentate N-Oxides.
    Nakajima, M.; Yokota, T.; Saito, M.; Hashimoto, S. Tetrahedron Lett. 2004, 45, 61-64.

  • A New Dirhodium(II) Carboxamidate Complex as a Chiral Lewis Acid Catalyst for Enantioselective Hetero-Diels-Alder Reactions.
    Anada, M.; Washio, T.; Shimada, N.; Kitagaki, S.; Nakajima, M.; Shiro, M.; Hashimoto, S. Angew. Chem. Int. Ed. 2004, 43, 2665-2668.

  • The Enantioselective Aldol Reaction of Trimethoxysilyl Enol Ether Catalyzed by Lithium Binaphtholate.
    Nakajima, M.; Orito, Y.; Ishizuka, T.: Hashimoto, S. Org. Lett.. 2004, 6, 3763-3765.

  • ルイス塩基として機能する不斉有機触媒.
    中島 誠, 化学と工業, 2004, 57, 720-723.